C points, characterized by circular polarization in momentum space, play crucial roles in chiral wave manipulations. However, conventional approaches of achieving intrinsic C points using photonic crystals with broken symmetries suffer from low Q factor and are highly sensitive to structural geometry, rendering them fragile and susceptible to perturbations and disorders. In this letter, we report the realization of magneto-optical (MO) bound states in the continuum (BICs) using a symmetry-preserved planar photonic crystal, achieving intrinsic at-\Gamma C points that are robust against variation in structural geometry and external magnetic field. MO coupling between two dipole modes induces Zeeman splitting of the eigenfrequencies, leading to MO BICs and quasi-BICs with circular eigenstates for high-Q chiral responses. Furthermore, switchable C point handedness and circular dichroism are enabled by reversing the magnetic field. These findings unveil a new type of BICs with circular eigenstates and on-demand control of C points, paving the way for advanced chiral wave manipulation with enhanced light-matter interaction.
Given the untapped potential for continuous improvement of examinations, quantitative investigations of examinations could guide efforts to considerably improve learning efficiency and evaluation and thus greatly help both learners and educators. However, there is a general lack of quantitative methods for investigating examinations. To address this gap, we propose a new metric via complex networks; i.e., the knowledge point network (KPN) of an examination is constructed by representing the knowledge points (concepts, laws, etc.) as nodes and adding links when these points appear in the same question. Then, the topological quantities of KPNs, such as degree, centrality, and community, can be employed to systematically explore the structural properties and evolution of examinations. In this work, 35 physics examinations from the NCEE examination spanning from 2006 to 2020 were investigated as an evidence. We found that the constructed KPNs are scale-free networks that show strong assortativity and small-world effects in most cases. The communities within the KPNs are obvious, and the key nodes are mainly related to mechanics and electromagnetism. Different question types are related to specific knowledge points, leading to noticeable structural variations in KPNs. Moreover, changes in the KPN topology between examinations administered in different years may offer insights guiding college entrance examination reforms. Based on topological quantities such as the average degree, network density, average clustering coefficient, and network transitivity, the Fd is proposed to evaluate examination difficulty. All the above results show that our approach can comprehensively quantify the knowledge structures and examination characteristics. These networks may elucidate comprehensive examination knowledge graphs for educators and guide improvements in teaching.
We demonstrate a compact ion beam device capable of accelerating H$^+$ and D$^+$ ions up to 75keV energy, on to a solid target, with sufficient beam current to study fusion reactions. The ion beam system uses a microwave driven plasma source to generate ions that are accelerated to high energy with a direct current (DC) acceleration structure. The plasma source is driven by pulsed microwaves from a solid-state radiofrequency (RF) amplifier, which is impedance matched to the plasma source chamber at the ISM band frequency (2.4-2.5GHz). The plasma chamber is held at high positive DC potential and is isolated from the impedance matching structure (at ground potential) by a dielectric-filled gap. To facilitate the use of high-energy-particle detectors near the target, the plasma chamber is biased to a high positive voltage, while the target remains grounded. A target loaded with deuterium is used to study D-D fusion and a B$_4$C or LaB$_6$ target is used to study p-$^{11}$B fusion. Detectors include solid-state charged particle detector and a scintillation fast neutron detector. The complete ion beam system can fit on a laboratory table and is a useful tool for teaching undergraduate and graduate students about the physics of fusion.
In this work, we utilize thin dielectric meta-atoms placed on a silver substrate to efficiently enhance and manipulate the third harmonic generation. We theoretically and experimentally reveal that when the structural symmetry of the meta-atom is incompatible with the lattice symmetry of an array, some generalized nonlinear geometric phases appear, which offers new possibilities for harmonic generation control beyond the accessible symmetries governed by the selection rule. The underlying mechanism is attributed to the modified rotation of the effective principal axis of a dense meta-atom array, where the strong coupling among the units gives rise to a generalized linear geometric phase modulation on the pump light. Therefore, nonlinear geometric phases carried by the third-harmonic emissions are the natural result of the wave-mixing process among the modes excited at the fundamental frequency. This mechanism further points out a new strategy to predict the nonlinear geometric phases delivered by the nanostructures according to their linear responses. Our design is simple and efficient, and offers alternatives for the nonlinear meta-devices that are capable of flexible photon generation and manipulation.
Jie Liu, Zufeng Pang, Zhiyong Li, Guilin Wen, Zhoucheng Su, Junfeng He, Kaiyue Liu, Dezheng Jiang, Zenan Li, Shouyan Chen, Yang Tian, Yi Min Xie, Zhenpei Wang, Zhuangjian Liu Origami-inspired robots with multiple advantages, such as being lightweight, requiring less assembly, and exhibiting exceptional deformability, have received substantial and sustained attention. However, the existing origami-inspired robots are usually of limited functionalities and developing feature-rich robots is very challenging. Here, we report an origami-wheeled robot (OriWheelBot) with variable width and outstanding sand walking versatility. The OriWheelBot's ability to adjust wheel width over obstacles is achieved by origami wheels made of Miura origami. An improved version, called iOriWheelBot, is also developed to automatically judge the width of the obstacles. Three actions, namely direct pass, variable width pass, and direct return, will be carried out depending on the width of the channel between the obstacles. We have identified two motion mechanisms, i.e., sand-digging and sand-pushing, with the latter being more conducive to walking on the sand. We have systematically examined numerous sand walking characteristics, including carrying loads, climbing a slope, walking on a slope, and navigating sand pits, small rocks, and sand traps. The OriWheelBot can change its width by 40%, has a loading-carrying ratio of 66.7% on flat sand and can climb a 17-degree sand incline. The OriWheelBot can be useful for planetary subsurface exploration and disaster area rescue.
Photoassociation of ultracold atoms is a resonant light-assisted collision process, in which two colliding atoms absorb a photon and form an excited molecule. Since the first observation about three decades ago, the photoassociation of ultracold atoms has made a significant impact on the study of ultracold atoms and molecules. Extending the photoassociation of atoms to the photoassociation of atom-molecule pairs or molecule-molecule pairs will offer many new opportunities in the study of precision polyatomic molecular spectroscopy, formation of ultracold polyatomic molecules, and quantum control of molecular collisions and reactions. However, the high density of states and the photoexcitation of the collision complex by the trapping laser make photoassociation into well-defined quantum states of polyatomic molecules extremely difficult. Here we report on the observation of photoassociation resonances in ultracold collisions between $^{23}$Na$^{40}$K molecules and $^{40}$K atoms. We perform photoassociation in a long-wavelength optical dipole trap to form deeply bound triatomic molecules in the electronically excited states. The atom-molecule Feshbach resonance is used to enhance the free-bound Franck-Condon overlap. The photoassociation into well-defined quantum states of excited triatomic molecules is identified by observing resonantly enhanced loss features. These loss features depend on the polarization of the photoassociation lasers, allowing us to assign the rotational quantum numbers. The observation of ultracold atom-molecule photoassociation resonances paves the way toward preparing ground-state triatomic molecules, provides a new high-resolution spectroscopy technique for polyatomic molecules, and is also important to atom-molecule Feshbach resonances.
In this study, we present a well-defined methodology for conducting Operando X-ray absorption near-edge structure spectroscopy (XANES) in conjunction with transmission X-ray nano computed tomography (TXM-nanoCT) experiments on the LiNi$_{0.5}$Mn$_{0.3}$Co$_{0.2}$O$_2$ (NMC) cathode electrode. To minimize radiation-induced damage to the sample during charge and discharge cycles and to gain a comprehensive 3D perspective of the (de)lithiation process of the active material, we propose a novel approach that relies on employing only three energy levels, strategically positioned at pre-edge, edge, and post-edge. By adopting this technique, we successfully track the various (de)lithiation states within the three-dimensional space during partial cycling. Furthermore, we are able to extract the nanoscale lithium distribution within individual secondary particles. Our observations reveal the formation of a core-shell structure during lithiation and we also identify that not all surface areas of the particles exhibit activity during the process. Notably, lithium intercalation exhibits a distinct preference, leading to non-uniform lithiation degrees across different electrode locations. The proposed methodology is not limited to the NMC cathode electrode but can be extended to study realistic dedicated electrodes with high active material (AM) density, facilitating exploration and quantification of heterogeneities and inhomogeneous lithiation within such electrodes. This multi-scale insight into the (de)lithiation process and lithiation heterogeneities within the electrodes is expected to provide valuable knowledge for optimizing electrode design and ultimately enhancing electrode performance in the context of material science and battery materials research.
In the context of calling for low carbon emissions, lithium-ion batteries (LIBs) have been widely concerned as a power source for electric vehicles, so the fundamental science behind their manufacturing has attracted much attention in recent years. Calendering is an important step of the LIB electrode manufacturing process, and the changes it brings to the electrode microstructure and mechanical properties are worth studying. In this work, we reported the observed cracking of active material (AM) particles due to calendering pressure under ex situ nano-X-ray tomography experiments. We developed a 3D-resolved discrete element method (DEM) model with bonded connections to physically mimic the calendering process using real AM particle shapes derived from the tomography experiments. The DEM model can well predict the change of the morphology of the dry electrode under pressure, and the changes of the applied pressure and porosity are consistent with the experimental values. At the same time, the model is able to simulate the secondary AM particles cracking by the fracture of the bond under force. Our model is the first of its kind being able to predict the fracture of the secondary particles along the calendering process. This work provides a tool for guidance in the manufacturing of optimized LIB electrodes.
Lei Lei, Lei Zu, Guan-Wen Yuan, Zhao-Qiang Shen, Yi-Ying Wang, Yuan-Zhu Wang, Zhen-Bo Su, Wen-ke Ren, Shao-Peng Tang, Hao Zhou, Chi Zhang, Zhi-Ping Jin, Lei Feng, Yi-Zhong Fan, Da-Ming Wei Studies have proposed that there is evidence for cosmological coupling of black holes (BHs) with an index of $k\approx 3$; hence, BHs serve as the astrophysical source of dark energy. However, the data sample is limited for the redshifts of $\leq 2.5$. In recent years, the James Webb Space Telescope (JWST) has detected many high-redshift active galactic nuclei (AGNs) and quasars. Among the JWST NIRSpec-/NIRCam-resolved AGNs, three are determined to be in early-type host galaxies with a redshift of $z\sim 4.5--7$. However, their $M_{\star}$ and $M_{\rm BH}$ are in tension with the predicted cosmological coupling of black holes with $k = 3$ at a confidence level of $\sim 2\sigma$, which challenges the hypothesis that BHs serve as the origin of dark energy. Future work on high-redshift AGNs using the JWST will further assess such a hypothesis by identifying more early-type host galaxies in the higher mass range.
Yutian Chi, Chenglong Shen, Long Cheng, Bingkun Yu, Bin Miao, Yuming Wang, Tielong Zhang, Zhuxuan Zou, Mengjiao Xu, Zonghao Pan, Zhenpeng Su, Jingnan Guo, Dongwei Mao, Zhihui Zhong, Zhiyong Zhang, Junyan Liu, Can Wang, Zhiyong Wu, Guoqiang Wang, Sudong Xiao, et al (5) Tianwen-1 spacecraft (Wan et al. 2020) is China's first Mars exploration mission. The Mars Orbiter Magnetometer (MOMAG) is a scientific instrument aboard the Tianwen-1 mission that is designed to study magnetic fields at Mars, including the solar wind to the magnetosheath and the ionosphere. Using the first Tianwen-1/MOMAG data that is publicly available, we present interplanetary coronal mass ejection (ICME) and stream interaction region (SIR) catalogues based on in-situ observations at Mars between November 16, 2021, and December 31, 2021. We compared the magnetic field intensity and vector magnetic field measurements from Tianwen-1/MOMAG and Mars Atmospheric Volatile EvolutioN (MAVEN)/MAG during the ICME and SIR interval and found a generally good consistency between them. Due to MAVEN's orbital adjustment since 2019, the Tianwen-1/MOMAG instrument is currently the almost unique interplanetary magnetic field monitor at Mars. The observations indicate that the MOMAG instrument on Tianwen-1 is performing well and can provide accurate measurements of the vector magnetic field in the near-Mars solar wind space. The multi-point observations combining MOMAG, MINPA, and MEPA on board Tianwen-1 with MAG, SWIA, and STATIC on board MAVEN will open a window to systematically study the characteristic of ICMEs and SIRs at Mars, and their influences on the Martian atmosphere and ionosphere.
Li-O$_2$ batteries (LOB) performance degradation ultimately occurs through the accumulation of discharge products and irreversible clogging of the porous electrode during the cycling. Electrode binder degradation in the presence of reduced oxygen species can result in additional coating of the conductive surface, exacerbating capacity fading. Herein, we establish a facile method to fabricate free-standing, binder-free electrodes for LOBs in which multi-wall carbon nanotubes (MWCNT) form cross-linked networks exhibiting high porosity, conductivity, and flexibility. These electrodes demonstrate high reproducibility upon cycling in LOBs. After cell death, efficient and inexpensive methods to wash away the accumulated discharge products are demonstrated, as reconditioning method. The second life usage of these electrodes is validated, without noticeable loss of performance. These findings aim to assist in the development of greener high energy density batteries while reducing manufacturing and recycling costs.
Zhuxuan Zou, Yuming Wang, Tielong Zhang, Guoqiang Wang, Sudong Xiao, Zonghao Pan, Zhoubin Zhang, Wei Yan, Yang Du, Yutian Chi, Long Cheng, Zhiyong Wu, Xinjun Hao, Yiren Li, Kai Liu, Manming Chen, Zhenpeng Su, Chenglong Shen, Mengjiao Xu, Jingnan Guo Mars Orbiter Magnetometer (MOMAG) is one of seven science payloads onboard Tianwen-1's orbiter. Unlike most of the satellites, Tianwen-1's orbiter is not magnetically cleaned, and the boom where placed the magnetometer's sensors is not long enough. These pose many challenges to the magnetic field data processing. In this paper, we introduce the in-flight calibration process of the Tianwen-1/MOMAG. The magnetic interference from the spacecraft, including spacecraft generated dynamic field and slowly-changing offsets are cleaned in sequence. Then the calibrated magnetic field data are compared with the data from the Mars Atmosphere and Volatile EvolutioN (MAVEN). We find that some physical structures in the solar wind are consistent between the two data sets, and the distributions of the magnetic field strength in the solar wind are very similar. These results suggest that the in-flight calibration of the MOMAG is successful and the MOMAG provides reliable data for scientific research.
Yuming Wang, Tielong Zhang, Guoqiang Wang, Sudong Xiao, Zhuxuan Zou, Long Cheng, Zonghao Pan, Kai Liu, Xinjun Hao, Yiren Li, Manming Chen, Zhoubin Zhang, Wei Yan, Zhenpeng Su, Zhiyong Wu, Chenglong Shen, Yutian Chi, Mengjiao Xu, Jingnan Guo, Yang Du Mars Orbiter MAGnetometer (MOMAG) is a scientifc instrument onboard the orbiter of China's first mission for Mars -- Tianwen-1. It started to routinely measure the magnetic field from the solar wind to magnetic pile-up region surrounding Mars since November 13, 2021. Here we present its in-flight performance and first science results based on the first one and a half months' data. By comparing with the magnetic field data in the solar wind from the Mars Atmosphere and Volatile EvolutioN (MAVEN), the magnetic field by MOMAG is at the same level in magnitude, and the same magnetic structures with the similar variations in three components could be found in MOMAG data. In the first one and a half months, we recognize 158 clear bow shock (BS) crossings from MOMAG data, whose locations statistically match well with the modeled average BS. We also identify 5 pairs of simultaneous BS crossings of the Tianwen-1's orbiter and MAVEN. These BS crossings confirm the global shape of modeled BS as well as the south-north asymmetry of the Martian BS. Two presented cases in this paper suggest that the BS is probably more dynamic at flank than near the nose. So far, MOMAG performs well, and provides accurate magnetic field vectors. MOMAG is continuously scanning the magnetic field surrounding Mars. These measurements complemented by observations from MAVEN will undoubtedly advance our understanding of the plasma environment of Mars.
The motion of a vibrating object is determined by the way it is held. This simple observation has long inspired string instrument makers to create new sounds by devising elegant string clamping mechanisms, whereby the distance between the clamping points is modulated as the string vibrates. At the nanoscale, the simplest way to emulate this principle would be to controllably make nanoresonators slide across their clamping points, which would effectively modulate their vibrating length. Here, we report measurements of flexural vibrations in nanomechanical resonators that reveal such a sliding motion. Surprisingly, the resonant frequency of vibrations draws a loop as a tuning gate voltage is cycled. This behavior indicates that sliding is accompanied by a delayed frequency response of the resonators, making their dynamics richer than that of resonators with fixed clamping points. Our work elucidates the dynamics of nanomechanical resonators with unconventional boundary conditions, and offers opportunities for studying friction at the nanoscale from resonant frequency measurements.
We report on the preparation of a quantum degenerate mixture of $^{23}$Na$^{40}$K molecules and $^{40}$K atoms. A deeply degenerate atomic mixture of $^{23}$Na and $^{40}$K atoms with a large number ratio ($N_F/N_B\approx 6$) is prepared by the mode-matching loading of atoms from a cloverleaf-type magnetic trap into a large-volume horizontal optical dipole trap and evaporative cooling in a large-volume three-beam optical dipole trap. About $3.0\times10^4$ $^{23}$Na$^{40}$K ground-state molecules are created through magneto-association followed by stimulated adiabatic Raman passage. The 2D density distribution of the molecules is fit to the Fermi-Dirac distribution with $T/T_F\approx0.4-0.5$. In the atom-molecule mixture, the elastic collisions provide a thermalization mechanism for the molecules. In a few tens of milliseconds which are larger than the typical thermalization time, the degeneracy of the molecules is maintained, which may be due to the Pauli exclusion principle. The quantum degenerate mixture of $^{23}$Na$^{40}$K molecules and $^{40}$K atoms can be used to study strongly interacting atom-molecule mixtures and to prepare ultracold triatomic molecular gases.
Microstructural evolution of NMC secondary particles during the battery operation drives the electrochemical performance and impacts the Li-ion battery lifetime. In this work, we develop an in situ methodology using the FIB/SEM instrument to cycle single secondary particles of NMC active materials while following the modifications of their 3D morphology. Two types of secondary particles, i.e. low and high gradient NMC, were studied alongside morphological investigations in both pristine state and different number of cycles. The quantification of initial inner porosity and cracking evolution upon electrochemical cycling reveals a clear divergence depending on the type of gradient particles. An unexpected enhancement of the discharge capacity is observed during the first cycles concurrently to the appearance of inner cracks. At the first stages, impedance spectroscopy shows a charge transfer resistance reduction that suggests a widening of the crack network connected to the surface, which leads to an increase of contact area between liquid electrolyte and NMC particle. 3D microstructure of individual secondary particles after in situ cycles were investigated using FIB/SEM and nano-XCT. The results suggest a strong impact of the initial porosity shape on the degradation rate.
We present a one-dimensional coupled ring resonator lattice exhibiting a variant of the non- Hermitian skin effect (NHSE) that we call the anomalous Floquet NHSE. Unlike existing approaches to achieving the NHSE by engineering gain and loss on different ring segments, our design uses fixed on-site gain or loss in each ring. The anomalous Floquet NHSE is marked by the existence of skin modes at every value of the Floquet quasienergy, allowing for broadband asymmetric transmission. Varying the gain/loss induces a non-Hermitian topological phase transition, reversing the localization direction of the skin modes. An experimental implementation in an acoustic lattice yields good agreement with theoretical predictions, with a very broad relative bandwidth of around 40%.
We have demonstrated the resonant control of the elastic scattering cross sections in the vicinity of Feshbach resonances between $^{23}$Na$^{40}$K molecules and $^{40}$K atoms by studying the thermalization between them. The elastic scattering cross sections vary by more than two orders of magnitude close to the resonance, and can be well described by an asymmetric Fano profile. The parameters that characterize the magnetically tunable s-wave scattering length are determined from the elastic scattering cross sections. The observation of resonantly controlled elastic scattering cross sections opens up the possibility to study strongly interacting atom-molecule mixtures and improve our understanding of the complex atom-molecule Feshbach resonances.
Optical geometric-phase metasurface provides a robust and efficient means for light control by simply manipulating the spatial orientations of the in-plane anisotropic meta-atoms, where polarization conversion plays a vital role. However, the concept of acoustic geometric-phase modulation for acoustic field control remains unexplored because airborne acoustic waves lack a similar optical polarization conversion process. In this work, a new type of acoustic meta-atom with deep subwavelength feature size is theoretically investigated and further applied to acoustic field engineering based on the so-called acoustic geometric phase. Herein, tunable acoustic geometric-phase modulation of designated order is obtained via the near-field coupled orbital angular momentum transfer process, and the topological charge-multiplexed acoustic geometric phase endows our meta-arrays with multiple functionalities. Our work extends the capacity of acoustic meta-arrays in high-quality acoustic field reconstruction and offers new possibilities in multifunctional acoustic meta-holograms.
The identification of regions of similar climatological behavior can be utilized for the discovery of spatial relationships over long-range scales, including teleconnections. In this regard, the global picture of the interdependence patterns of extreme rainfall events (EREs) still needs to be further explored. To this end, we propose a top-down complex-network-based clustering workflow, with the combination of consensus clustering and mutual correspondences. Consensus clustering provides a reliable community structure under each dataset, while mutual correspondences build a matching relationship between different community structures obtained from different datasets. This approach ensures the robustness of the identified structures when multiple datasets are available. By applying it simultaneously to two satellite-derived precipitation datasets, we identify consistent synchronized structures of EREs around the globe, during boreal summer. Two of them show independent spatiotemporal characteristics, uncovering the primary compositions of different monsoon systems. They explicitly manifest the primary intraseasonal variability in the context of the global monsoon, in particular the `monsoon jump' over both East Asia and West Africa and the mid-summer drought over Central America and southern Mexico. Through a case study related to the Asian summer monsoon (ASM), we verify that the intraseasonal changes of upper-level atmospheric conditions are preserved by significant connections within the global synchronization structure. Our work advances network-based clustering methodology for (i) decoding the spatiotemporal configuration of interdependence patterns of natural variability and for (ii) the intercomparison of these patterns, especially regarding their spatial distributions over different datasets.
Measurement-based quantum communication relies on the availability of highly entangled multi-photon cluster states. The inbuilt redundancy in the cluster allows communication between remote nodes using repeated local measurements, compensating for photon losses and probabilistic Bell-measurements. For feasible applications, the cluster generation should be fast, deterministic, and its photons - indistinguishable. We present a novel source based on a semiconductor quantum-dot device. The dot confines a heavy-hole, precessing in a finely tuned external weak magnetic field while periodically excited by a sequence of optical pulses. Consequently, the dot emits indistinguishable polarization-entangled photons, where the field strength optimizes the entanglement. We demonstrate Gigahertz rate deterministic generation of >90% indistinguishable photons in a cluster state with more than 10 photons characteristic entanglement-length.
Metasurfaces based on geometric phase acquired from the conversion of the optical spin states provide a robust control over the wavefront of light, and have been widely employed for construction of various types of functional metasurface devices. However, this powerful approach cannot be readily transferred to the manipulation of acoustic waves because acoustic waves do not possess the spin degree of freedom. Here, we propose the concept of acoustic geometric-phase meta-array by leveraging the conversion of orbital angular momentum of acoustic waves, where well-defined geometric-phases can be attained through versatile topological charge conversion processes. This work extends the concept of geometric-phase metasurface from optics to acoustics, and provides a new route for acoustic wave control.
Ultracold assembly of diatomic molecules has enabled great advances in controlled chemistry, ultracold chemical physics, and quantum simulation with molecules. Extending the ultracold association to triatomic molecules will offer many new research opportunities and challenges in these fields. A possible approach is to form triatomic molecules in the ultracold atom and diatomic molecule mixture by employing the Feshbach resonance between them. Although the ultracold atom-diatomic-molecule Feshbach resonances have been observed recently, utilizing these resonances to form triatomic molecules remains challenging. Here we report on the evidence of the association of triatomic molecules near the Feshbach resonances between $^{23}$Na$^{40}$K molecules in the rovibrational ground state and $^{40}$K atoms. We apply a radio-frequency pulse to drive the free-bound transition and monitor the loss of $^{23}$Na$^{40}$K molecules. The association of triatomic molecules manifests itself as an additional loss feature in the radio-frequency spectra, which can be distinguished from the atomic loss feature.The binding energy of triatomic molecule is estimated from the measurement. Our work is helpful to understand the complex ultracold atom-molecule Feshbach resonance and may open up an avenue towards the preparation and control of ultracold triatomic molecules.
Zhengxiong Su, Jun Ding, Miao Song, Li Jiang, Tan Shi, Zhiming Li, Sheng Wang, Fei Gao, Di Yun, Chenyang Lu, En Ma High-entropy alloys (HEAs) composed of multiple principal elements have been shown to offer improved radiation resistance over their elemental or dilute-solution counterparts. Using NiCoFeCrMn HEA as a model, here we introduce carbon and nitrogen interstitial alloying elements to impart chemical heterogeneities in the form of the local chemical order (LCO) and associated compositional variations. Density functional theory simulations predict chemical short-range order (CSRO) (nearest neighbors and the next couple of atomic shells) surrounding C and N, due to the chemical affinity of C with (Co, Fe) and N with (Cr, Mn). Atomic-resolution chemical mapping of the elemental distribution confirms marked compositional variations well beyond statistical fluctuations. Ni+ irradiation experiments at elevated temperatures demonstrate a remarkable reduction in void swelling by at least one order of magnitude compared to the base HEA without C and N alloying. The underlying mechanism is that the interstitial-solute-induced chemical heterogeneities roughen the lattice as well as the energy landscape, impeding the movements of, and constraining the path lanes for, the normally fast-moving self-interstitials and their clusters. The irradiation-produced interstitials and vacancies therefore recombine more readily, delaying void formation. Our findings thus open a promising avenue towards highly radiation-tolerant alloys.
Xin-Yao Wang, Matthew D. Frye, Zhen Su, Jin Cao, Lan Liu, De-Chao Zhang, Huan Yang, Jeremy M. Hutson, Bo Zhao, Chun-Li Bai, Jian-Wei Pan We present measurements of more than 80 magnetic Feshbach resonances in collisions of ultracold $^{23}$Na$^{40}$K with $^{40}$K. We assign quantum numbers to a group of low-field resonances and show that they are due to long-range states of the triatomic complex in which the quantum numbers of the separated atom and molecule are approximately preserved. The resonant states are not members of chaotic bath of short-range states. Similar resonances are expected to be a common feature of alkali-metal diatom + atom systems.
Geothermal heat, as renewable energy, shows great advantage with respect to its environmental impact due to its significantly lower CO2 emissions than conventional fossil fuel. Open and closed-loop geothermal heat pumps, which utilize shallow geothermal systems, are an efficient technology for cooling and heating buildings, especially in urban areas. Integrated use of geothermal energy technologies for district heating, cooling, and thermal energy storage can be applied to optimize the subsurface for communities to provide them with multiple sustainable energy and community resilience benefits. The utilization of the subsurface resources may lead to a variation in the underground environment, which might further impact local environmental conditions. However, very few simulators can handle such a highly complex set of coupled computations on a regional or city scale. We have developed high-performance computing (HPC) based hydrothermal finite element (FE) simulator that can simulate the subsurface and its hydrothermal conditions at a scale of tens of km. The HPC simulator enables us to investigate the subsurface thermal and hydrologic response to the built underground environment (such as basements and subways) at the community scale. In this study, a coupled hydrothermal simulator is developed based on the open-source finite element library deal.II. The HPC simulator was validated by comparing the results of a benchmark case study against COMSOL Multiphysics, in which Aquifer Thermal Energy Storage (ATES) is modeled and a process of heat injection into ATES is simulated. The use of an energy pile system at the Treasure Island redevelopment site (San Francisco, CA, USA) was selected as a case study to demonstrate the HPC capability of the developed simulator. The simulator is capable of modeling multiple city-scale geothermal scenarios in a reasonable amount of time.
Surface dielectric barrier discharge (SDBD) actuators driven by the Pulsed-DC voltages are analyzed. The Pulsed-DC SDBD studied in this work is equivalent to a classical SDBD driven by a tailored Fast-Rise-Slow-Decay (FRSD) voltage waveform. The plasma channel formation and charge production process in the voltage rising stage are studied at different slopes using a classical 2D fluid model, the thrust generated in the voltage decaying stage is studied based on an analytical approach taking 2D model results as the input. A thrust pulse is generated in the trailing edge of the voltage waveform and reaches maximum when the voltage decreases by approximately the value of cathode voltage fall~($\approx$600~V). The time duration of the rising and trailing edge, the decay rate and the amplitude of applied voltage are the main factors affecting the performance of the actuator. Analytical expressions are formulated for the value and time moment of peak thrust, the upper limit of thrust is also estimated. Higher voltage rising rate leads to higher charge density in the voltage rising stage thus higher thrust. Shorter voltage trailing edge, in general, results in higher value and earlier appearance of the peak thrust. The detailed profile of the trailing edge also affects the performance. Results in this work allow us to flexibly design the FRSD waveforms for an SDBD actuator according to the requirements of active flow control in different application conditions.
Analyzing and mining students' behaviors and interactions from big data is an essential part of education data mining. Based on the data of campus smart cards, which include not only static demographic information but also dynamic behavioral data from more than 30000 anonymous students, in this paper, the evolution features of friendship and the relations between behavior characters and student interactions are investigated. On the one hand, four different evolving friendship networks are constructed by means of the friend ties proposed in this paper, which are extracted from monthly consumption records. In addition, the features of the giant connected components (GCCs) of friendship networks are analyzed via social network analysis (SNA) and percolation theory. On the other hand, two high-level behavior characters, orderliness and diligence, are adopted to analyze their associations with student interactions. Our experiment/empirical results indicate that the sizes of friendship networks have declined with time growth and both the small-world effect and power-law degree distribution are found in friendship networks. Second, the results of the assortativity coefficient of both orderliness and diligence verify that there are strong peer effects among students. Finally, the percolation analysis of orderliness on friendship networks shows that a phase transition exists, which is enlightening in that swarm intelligence can be realized by intervening the key students near the transition point.
Zhirui Su, Rulei Xiao, Zhenxing Sun, Zijiang Yang, Yinchao Du, Zhao Chen, Jilin Zheng, Yunshan Zhang, Jun Lu, Yuechun Shi, Yi-Jen Chiu, Xiangfei Chen We report a 48-channel 100-GHz tunable laser near 1550 nm by integrating 16 DFB lasers. High wavelength-spacing uniformity is guaranteed by the reconstruction-equivalent-chirp technique, which enables a temperature tuning range below 20 Celsius degree.
Air quality impacts people's health and daily life, affects the sensitive ecosystems, and even restrains a country's development. By collecting and processing the time series data of Air Quality Index (AQI) of 363 cities of China from Jan. 2015 to Mar. 2019, we dedicated to characterize the universal patterns, the clustering and correlation of air quality of different cities by using the methods of complex network and time series analysis. The main results are as follows: 1) The Air Quality Network of China (AQNC) is constructed by using the Planar Maximally Filtered Graph (PMFG) method. The geographical distances on the correlation of air quality of different cities have been studied, it is found that 100 km is a critical distance for strong correlation. 2) Seven communities of AQNC have been detected, and their patterns have been analyzed by taking into account the Hurst exponent and climate environment, it is shown that the seven communities are reasonable, and they are significantly influenced by the climate factors, such as monsoon, precipitation, geographical regions, etc. 3) The motifs of air quality time series of seven communities have been investigated by the visibility graph, for some communities, the evolutionary patterns of the motifs are a bit stable, and they have the long-term memory effects. While for others, there are no stable patterns.
Parametric amplification is widely used in nanoelectro-mechanical systems to enhance the transduced mechanical signals. Although parametric amplification has been studied in different mechanical resonator systems, the nonlinear dynamics involved receives less attention. Taking advantage of the excellent electrical and mechanical properties of graphene, we demonstrate electrical tunable parametric amplification using a doubly clamped graphene nanomechanical resonator. By applying external microwave pumping with twice the resonant frequency, we investigate parametric amplification in the nonlinear regime. We experimentally show that the extracted coefficient of the nonlinear Duffing force \alpha and the nonlinear damping coefficient \eta vary as a function of external pumping power, indicating the influence of higher-order nonlinearity beyond the Duffing (~x^3) and van der Pol (~x^2 dx/dt) types in our device. Even when the higher-order nonlinearity is involved, parametric amplification still can be achieved in the nonlinear regime. The parametric gain increases and shows a tendency of saturation with increasing external pumping power. Further, the parametric gain can be electrically tuned by the gate voltage with a maximum gain of 10.2 dB achieved at the gate voltage of 19 V. Our results will benefit studies on nonlinear dynamics, especially nonlinear damping in graphene nanomechanical resonators that has been debated in the community over past decade.
Han-Sen Zhong, Yuan Li, Wei Li, Li-Chao Peng, Zu-En Su, Yi Hu, Yu-Ming He, Xing Ding, W.-J. Zhang, Hao Li, L. Zhang, Z. Wang, L.-X. You, Xi-Lin Wang, Xiao Jiang, Li Li, Yu-Ao Chen, Nai-Le Liu, Chao-Yang Lu, Jian-Wei Pan Entangled photon sources with simultaneously near-unity heralding efficiency and indistinguishability are the fundamental elements for scalable photonic quantum technologies. We design and realize a degenerate entangled-photon source from an ultrafast pulsed laser pumped spontaneous parametric down-conversion (SPDC), which show simultaneously ~97% heralding efficiency and ~96% indistinguishability between independent single photons. Such a high-efficiency and frequency-uncorrelated SPDC source allows generation of the first 12-photon genuine entanglement with a state fidelity of 0.572(24). We further demonstrate a blueprint of scalable scattershot boson sampling using 12 SPDC sources and a 12*12-modes interferometer for three-, four-, and five-boson sampling, which yields count rates more than four orders of magnitudes higher than all previous SPDC experiments. Our work immediately enables high-efficiency implementations of multiplexing, scattershot boson sampling, and heralded creation of remotely entangled photons, opening up a promising pathway to scalable photonic quantum technologies.
Community structure is an important factor in the behavior of real-world networks because it strongly affects the stability and thus the phase transition order of the spreading dynamics. We here propose a reversible social contagion model of community networks that includes the factor of social reinforcement. In our model an individual adopts a social contagion when the number of received units of information exceeds its adoption threshold. We use mean-field approximation to describe our proposed model, and the results agree with numerical simulations. The numerical simulations and theoretical analyses both indicate that there is a first-order phase transition in the spreading dynamics, and that a hysteresis loop emerges in the system when there is a variety of initially-adopted seeds. We find an optimal community structure that maximizes spreading dynamics. We also find a rich phase diagram with a triple point that separates the no-diffusion phase from the two diffusion phases.
An adaptive label propagation algorithm (ALPA) is proposed to detect and monitor communities in dynamic networks. Unlike the traditional methods by re-computing the whole community decomposition after each modification of the network, ALPA takes into account the information of historical communities and updates its solution according to the network modifications via a local label propagation process, which generally affects only a small portion of the network. This makes it respond to network changes at low computational cost. The effectiveness of ALPA has been tested on both synthetic and real-world networks, which shows that it can successfully identify and track dynamic communities. Moreover, ALPA could detect communities with high quality and accuracy compared to other methods. Therefore, being low-complexity and parameter-free, ALPA is a scalable and promising solution for some real-world applications of community detection in dynamic networks.
We demonstrated a 2D helical chiral metamaterial that exhibits broadband strong optical activity resulting nonresonant Drude-like response. The strong chirality leads to broadband negative refractive index with high figure of merit (>90) and extremely low loss (<2% per layer). The optical activity are insensitive to the angles of incident electromagnetic waves, thereby enabling more flexibility in polarization manipulation applicaitons.
The label propagation algorithm (LPA) has been proved to be a fast and effective method for detecting communities in large complex networks. However, its performance is subject to the non-stable and trivial solutions of the problem. In this paper, we propose a modified label propagation algorithm LPAf to efficiently detect community structures in networks. Instead of the majority voting rule of the basic LPA, LPAf updates the label of a node by considering the compression of a description of random walks on a network. A multi-step greedy agglomerative strategy is employed to enable LPAf to escape the local optimum. Furthermore, an incomplete update condition is also adopted to speed up the convergence. Experimental results on both synthetic and real-world networks confirm the effectiveness of our algorithm.
Because of the strong inherent resonances, the giant optical activity obtained via chiral metamaterials generally suffers from high dispersion, which has been a big stumbling block to broadband applications. In this paper, we propose a type of chiral metamaterial consisting of interconnected metal helix structures with four-fold symmetry, which exhibits nonresonant Drude-like response and can therefore avoid the highly dispersive optical activity resulting from resonances. It shows that the well-designed chiral metamaterial can achieve nondispersive and pure optical activity with high transmittance in a broadband frequency range. And the optical activity of multi-layer chiral metamaterials is proportional to the layer numbers of single-layer chiral metamaterial. Most remarkably, the broadband behaviors of nondispersive optical activity and high transmission are insensitive to the incident angles of electromagnetic waves and permittivity of dielectric substrate, thereby enabling more flexibility in polarization manipulation.
Many models and real complex systems possess critical thresholds at which the systems shift from one sate to another. The discovery of the early warnings of the systems in the vicinity of critical point are of great importance to estimate how far a system is from a critical threshold. Multifractal Detrended Fluctuation analysis (MF-DFA) and visibility graph method have been employed to investigate the fluctuation and geometrical structures of magnetization time series of two-dimensional Ising model around critical point. The Hurst exponent has been confirmed to be a good indicator of phase transition. Increase of the multifractality of the time series have been observed from generalized Hurst exponents and singularity spectrum. Both Long-term correlation and broad probability density function are identified to be the sources of multifractality of time series near critical regime. Heterogeneous nature of the networks constructed from magnetization time series have validated the fractal properties of magnetization time series from complex network perspective. Evolution of the topology quantities such as clustering coefficient, average degree, average shortest path length, density, assortativity and heterogeneity serve as early warnings of phase transition. Those methods and results can provide new insights about analysis of phase transition problems and can be used as early warnings for various complex systems.
Quantum teleportation provides a "disembodied" way to transfer quantum states from one object to another at a distant location, assisted by priorly shared entangled states and a classical communication channel. In addition to its fundamental interest, teleportation has been recognized as an important element in long-distance quantum communication, distributed quantum networks and measurement-based quantum computation. There have been numerous demonstrations of teleportation in different physical systems such as photons, atoms, ions, electrons, and superconducting circuits. Yet, all the previous experiments were limited to teleportation of one degree of freedom (DoF) only. However, a single quantum particle can naturally possess various DoFs -- internal and external -- and with coherent coupling among them. A fundamental open challenge is to simultaneously teleport multiple DoFs, which is necessary to fully describe a quantum particle, thereby truly teleporting it intactly. Here, we demonstrate the first teleportation of the composite quantum states of a single photon encoded in both the spin and orbital angular momentum. We develop a method to project and discriminate hyper-entangled Bell states exploiting probabilistic quantum non-demolition measurement, which can be extended to more DoFs. We verify the teleportation for both spin-orbit product states and hybrid entangled state, and achieve a teleportation fidelity ranging from 0.57 to 0.68, above the classical limit. Our work moves a step toward teleportation of more complex quantum systems, and demonstrates an enhanced capability for scalable quantum technologies.
Yanan Wang, Zhihua Su, Wei Wu, Shu Nie, Xinghua Lu, Haiyan Wang, Kevin McCarty, Shin-shem Pei, Francisco Robles-Hernandez, Viktor G. Hadjiev, Jiming Bao We report the observation of anomalously strong 2D band in twisted bilayer graphene (tBLG) with large rotation angles under 638-nm and 532-nm visible laser excitation. The 2D band of tBLG can reach four times as opposed to two times as strong as that of single layer graphene. The same tBLG samples also exhibit rotation dependent G-line resonances and folded phonons under 364-nm UV laser excitation. We attribute this 2D band Raman enhancement to the constructive quantum interference between two double-resonance Raman pathways which are enabled by nearly degenerate Dirac band in tBLG Moiré superlattices.
Four large ring molecules composed by 15 nitrogen-substituted benzene rings, named as "knot-isomers of Moebius cyclacene", i.e. non-Moebius cyclacenes without a knot (0), Moebius cyclacenes with a knot (1), non-Moebius cyclacenes with two knots (2), and Moebius cyclacenes with three knots (3), are systematically studied for their structures and nonlinear optical properties. The first hyperpolarizability (beta_0) values of these four knot-isomers structures are 4693 (0) < 10484 (2) < 25419 (3) < 60846 au (1). The beta_0 values (60846 for 1, 10484 for 2 and 25419 au for 3) of the knot-isomers with knot(s) are larger than that (4693 au for 0) of the knot-isomer without a knot. It shows that the beta_0 value can be dramatically increases (13 times) by introducing the knot(s) to the cyclacenes structures. It is found that introducing knots to cyclacenes is a new means to enhance the first hyperpolarizability.
Lattice models, for their coarse-grained nature, are best suited for the study of the ``designability problem'', the phenomenon in which most of the about 16,000 proteins of known structure have their native conformations concentrated in a relatively small number of about 500 topological classes of conformations. Here it is shown that on a lattice the most highly designable simulated protein structures are those that have the largest number of surface-core switchbacks. A combination of physical, mathematical and biological reasons that causes the phenomenon is given. By comparing the most foldable model peptides with protein sequences in the Protein Data Bank, it is shown that whereas different models may yield similar designabilities, predicted foldable peptides will simulate natural proteins only when the model incorporates the correct physics and biology, in this case if the main folding force arises from the differing hydrophobicity of the residues, but does not originate, say, from the steric hindrance effect caused by the differing sizes of the residues.