Summary: We investigate three types of convergence for geometrically ergodic Markov chains (MCs) with countable state space, which in general lead to different ‘rates of convergence’. For reversible Markov chains it is shown that these rates coincide. For general MCs, we show some connections between their rates and those of the associated reversed MCs. Moreover, we study the relations between these rates and a certain family of isoperimetric constants. This sheds new light on the connection of geometric ergodicity and the so-called spectral gap property, in particular, for non-reversible MCs, and makes it possible to derive sharp upper and lower bounds for the spectral radius of certain non-reversible chains.