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Existence and construction of dynamical potential in nonequilibrium processes without detailed balance. (English) Zbl 1148.82016

Summary: The existence of a dynamical potential with both local and global meanings in general nonequilibrium processes has been controversial. Following an earlier heuristic argument in a letter by one of us, in the present paper we show rigorously its existence for a generic class of situations in physical and biological sciences. The local dynamical meaning of this potential function is demonstrated via a special stochastic differential equation and its global steady-state meaning via a novel and explicit form of the Fokker-Planck equation. We also give a procedure to obtain the special stochastic differential equation for any given Fokker-Planck equation. No detailed balance condition is required in our demonstration. For the first time we obtain here a formula to describe the noise-induced shift in drift force compared to the steady-state distribution, a phenomenon extensively observed in numerical studies.

MSC:

82C05 Classical dynamic and nonequilibrium statistical mechanics (general)
82C31 Stochastic methods (Fokker-Planck, Langevin, etc.) applied to problems in time-dependent statistical mechanics