Summary: Recently there has been much work on developing models that are suitable for analysing the volatility of a continuous time process. One general approach is to define a volatility process as the convolution of a kernel with a non-decreasing Lévy process, which is nonnegative if the kernel is nonnegative. Within the framework of time-continuous autoregressive moving average (CARMA) processes, we derive a necessary and sufficient condition for the kernel to be non-negative. This condition is in terms of the Laplace transform of the CARMA kernel, which has a simple form. We discuss some useful consequences of this result and delineate the parametric region of stationarity and non-negative kernels for some lower order CARMA models.