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Polymer entanglement in melts. (English) Zbl 0956.82031

Summary: We propose a new way of characterizing the entanglement complexity of concentrated polymer solutions and polymer melts. This involves considering a randomly chosen cube in the system, and investigating the entanglements between sub-chains in this cube. We present Monte Carlo calculations and scaling arguments for the density dependence of the entanglement complexity, and the way in which this behaviour scales with the size of the chosen cube.

MSC:

82D60 Statistical mechanics of polymers
Full Text: DOI