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Copper(I) acetate

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Copper(I) acetate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.009.036 Edit this at Wikidata
EC Number
  • 209-938-7
UNII
  • InChI=1S/C2H4O2.Cu/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
    Key: RFKZUAOAYVHBOY-UHFFFAOYSA-M
  • CC(=O)[O-].[Cu+]
Properties
C2H3CuO2
Molar mass 122.590 g·mol−1
Hazards
GHS labelling:[1]
GHS07: Exclamation mark
Warning
H315, H319, H335
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Copper(I) acetate (cuprous acetate) is an organic copper salt of acetic acid with chemical formula CH3COOCu.

Under standard conditions, copper(I) acetate is a colorless, odorless crystal.

Chemical propieties

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When interacting with water (hydrolysis), copper(I) hydroxide (CuOH) is formed:

CuCH3COO + H2O → CuOH + CH3COOH

In air, it oxidizes to copper(II) acetate. It forms adducts with organic substances.

Synthesis

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  • Reaction of copper(II) acetate with hydrogen or copper (reduction process):
2 (CH3COO)2Cu + H2 → 2 CH3COOCu + 2 CH3COOH
(CH3COO)2Cu + Cu → 2 CH3COOCu

Application

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Copper(I) acetate is used as a catalyst for the oxidation of phenols.

References

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  1. ^ "Copper(I) acetate". pubchem.ncbi.nlm.nih.gov.