Afghanite, (Na,K)22Ca10[Si24Al24O96](SO4)6Cl6,[2] is a hydrous sodium, calcium, potassium, sulfate, chloride, carbonate alumino-silicate mineral. Afghanite is a feldspathoid of the cancrinite group and typically occurs with sodalite group minerals. It forms blue to colorless, typically massive crystals in the trigonal crystal system. The lowering of the symmetry from typical (for cancrinite group) hexagonal one is due to ordering of Si and Al.[2] It has a Mohs hardness of 5.5 to 6 and a specific gravity of 2.55 to 2.65. It has refractive index values of nω = 1.523 and nε = 1.529. It has one direction of perfect cleavage and exhibits conchoidal fracture.[4] It fluoresces a bright orange.
| Afghanite | |
|---|---|
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| General | |
| Category | Tectosilicates |
| Formula (repeating unit) | (Na,K)22Ca10[Si24Al24O96](SO4)6Cl6 |
| IMA symbol | Afg[1] |
| Strunz classification | 9.FB.05 |
| Crystal system | Trigonal |
| Crystal class | Ditrigonal pyramidal (3m) H-M symbol: (3m) |
| Space group | P31c[2] |
| Unit cell | a = 12.796, c = 21.409 [Å]; Z = 1 |
| Identification | |
| Color | light blue, dark blue |
| Crystal habit | Lath shaped crystals, rounded grains |
| Cleavage | Perfect {1010} |
| Fracture | Conchoidal |
| Mohs scale hardness | 5.5–6 |
| Luster | Vitreous |
| Streak | white |
| Diaphaneity | Transparent |
| Specific gravity | 2.55–2.65 |
| Optical properties | Uniaxial (+) |
| Refractive index | nω = 1.523 nε = 1.529 |
| Birefringence | δ = 0.006 |
| Other characteristics |  Radioactive 2.28% (K) |
| References | [3][4][5][6] |
It was discovered in 1968 in the Lapis-lazuli Mine, Sar-e-Sang, Badakhshan Province, Afghanistan and takes its name from that country. It has also been described from localities in Germany, Italy, the Pamir Mountains of Tajikistan, near Lake Baikal in Siberia, New York and Newfoundland. It occurs as veinlets in lazurite crystals in the Afghan location and in altered limestone xenoliths within pumice in Pitigliano, Tuscany, Italy.[3]
It is used as a gemstone.[7]
See also
editReferences
edit- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ a b c Ballirano, Paolo; Bonaccorsi, Elena; Maras, Adriana; Merlino, Stefanο (1996). "Crystal structure of afghanite, the eight-layer member of the cancrinite-group: Evidence for long-range Si,Al ordering". European Journal of Mineralogy. 9 (1): 21–30. Bibcode:1996EJMin...9...21B. doi:10.1127/ejm/9/1/0021.
- ^ a b Mineral Data Publishing 2001
- ^ a b Mindat with location data
- ^ Webmineral data
- ^ "Radioactive Gems : ClassicGems.net".
- ^ Tables of Gemstone Identification, By Roger Dedeyne, Ivo Quintens, p.112