User:Graeme Bartlett/borate iodate
Note:There do not seem to be many of these yet. may have to wait a few years.
A borate iodate is a mixed anion compound containing both borate and iodate ions. Borate iodides were discovered in 2019.[1]
Complete as of August 2023
List
[edit]| formula | formula
weight |
system | space group | unit cell | volume | density | comment | references | |
|---|---|---|---|---|---|---|---|---|---|
| Be2(BO3)(IO3) | 251.73 | orthorhombic | Pmc21 | a=7.6958 b=7.2123 c=8.4647 Z=4 | 469.83 | 3.559 | SHG 7.2×KDP | [2] | |
| Sr[B(OH)4](IO3) | (μ-tetrahydrogen borate)-(μ-iodate)-strontium | 341.36 | triclinic | P1 | a =6.59 b =6.87 c =7.12 α=96.73° β=108.18° γ=92.37° Z=2 | 303.3 | 3.738 | white; UV cutoff 233 nm | [1] |
| Li4Sr5[B12O22(OH)4](IO3)2 | penta-strontium tetra-lithium bis(iodate) tetrahydridododecaborate | 1365.41 | monoclinic | C2/m | a=14.245 b=11.239 c =9.215 β=123.625° Z=2 | 1228.5 | 3.691 | white; UV cutoff 239 nm | [1] |
References
[edit]- ^ a b c Peng, Guang; Lin, Chensheng; Zhao, Dan; Cao, Liling; Fan, Huixin; Chen, Kaichuang; Ye, Ning (2019). "Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence". Chemical Communications. 55 (74): 11139–11142. doi:10.1039/C9CC05021C. ISSN 1359-7345.
- ^ Peng, Guang; Lin, Chensheng; Fan, Huixin; Chen, Kaichuang; Li, Bingxuan; Zhang, Ge; Ye, Ning (2021-08-02). "Be 2 (BO 3 )(IO 3 ): The First Anion‐mixed Van der Waals Member in the KBe 2 BO 3 F 2 Family with a Very Strong Second Harmonic Generation Response". Angewandte Chemie International Edition. 60 (32): 17415–17418. doi:10.1002/anie.202105777. ISSN 1433-7851.