In quantum field theory, the Polyakov loop is the thermal analogue of the Wilson loop, acting as an order parameter for confinement in pure gauge theories at nonzero temperatures. In particular, it is a Wilson loop that winds around the compactified Euclidean temporal direction of a thermal quantum field theory. It indicates confinement because its vacuum expectation value must vanish in the confined phase due to its non-invariance under center gauge transformations. This also follows from the fact that the expectation value is related to the free energy of individual quarks, which diverges in this phase. Introduced by Alexander M. Polyakov in 1975, they can also be used to study the potential between pairs of quarks at nonzero temperatures.
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