Desorption overshoot in polymer-penetrant systems: Asymptotic and computational results. (English) Zbl 1011.35011
Summary: Many practically relevant polymers undergoing desorption change from the rubbery (saturated) to the glassy (nearly dry) state. The dynamics of such systems cannot be described by the simple Fickian diffusion equation due to viscoelastic effects. The mathematical model solved numerically is a set of two coupled PDEs for concentration and stress. Asymptotic solutions are presented for a moving boundary-value problem for the two states in the short-time limit. The solutions exhibit desorption overshoot, where the penetrant concentration in the interior is less than that on the surface. In addition, it is shown that if the underlying time scale of the equations is ignored when postulating boundary conditions, nonphysical solutions can result.
MSC:
35B20 | Perturbations in context of PDEs |
35C20 | Asymptotic expansions of solutions to PDEs |
35K60 | Nonlinear initial, boundary and initial-boundary value problems for linear parabolic equations |
35R35 | Free boundary problems for PDEs |
65N30 | Finite element, Rayleigh-Ritz and Galerkin methods for boundary value problems involving PDEs |
74D10 | Nonlinear constitutive equations for materials with memory |
76M10 | Finite element methods applied to problems in fluid mechanics |
35C15 | Integral representations of solutions to PDEs |
80A22 | Stefan problems, phase changes, etc. |