×

Irreversible circulation of fluctuation and entropy production. (English) Zbl 1151.82349

Summary: Physical and chemical stochastic processes described by the master equation are investigated. The system-size expansion, called the \(\Omega\)-expansion, transforms the master equation to the corresponding Fokker-Planck equation. In this paper, we examine the entropy production for both the master equation and the corresponding Fokker-Planck equation. For the master equation, the exact expression of the entropy production was recently derived by P. Gaspard using Kolmogorov-Sinai entropy [J. Stat. Phys. 117, No. 3–4, 599–615 (2004; Zbl 1113.82036); Erratum ibid. 126, No. 4–5, 1109 (2007)]. Although Gaspard’s expression is derived from a stochastic consideration, it should be noted that it coincides with the thermodynamical expression. For the corresponding Fokker-Planck equation, by using the detailed imbalance relation, which appears in the process of deriving the fluctuation theorem through the Onsager-Machlup theory, the entropy production is expressed in terms of the irreversible circulation of fluctuation, which was proposed by K. Tomita and H. Tomita [Prog. Theor. Phys. 51, 1731 (1974), Errata; 53, 1546b (1975)]. However, this expression for the corresponding Fokker-Planck equation differs from that of the entropy production for the master equation. This discrepancy is due to the difference between the master equation and the corresponding Fokker-Planck equation, namely the former treats discrete events, but the latter equation is an approximation of the former one. In fact, in the latter equation, the original discrete events are smoothed out. To overcome this difficulty, we propose a hypothetical path weight principle. By using this principle, the modified expression of the entropy production for the corresponding Fokker-Planck equation coincides with that of the master equation (i.e., the thermodynamical expression) for a simple chemical reaction system and a diffusion system.

MSC:

82B35 Irreversible thermodynamics, including Onsager-Machlup theory

Citations:

Zbl 1113.82036

References:

[1] Graham, R.; Haken, H.: Z. phys.. 243, 289 (1971)
[2] Van Kampen, N. G.: Can. J. Phys.. 39, 551 (1961)
[3] Kubo, R.; Kotahara, K.; Matsuo, K.: J. stat. Phys.. 9, 51 (1973)
[4] Graham, R.: L.mandele.wolf coherence and quantum optics. Coherence and quantum optics, 851 (1973)
[5] E. Snitzer, Quantum electronics, ed. P. Grivet and N. Bloembergen, (Columbia University Press) vol. II, p. 999.
[6] Vavillin, A. A.; Zhabotinskii, A. M.: Kinet. katal.. 10, 657 (1969)
[7] K. Tomita, T. Oota and H. Tomita, to be published.
This reference list is based on information provided by the publisher or from digital mathematics libraries. Its items are heuristically matched to zbMATH identifiers and may contain data conversion errors. In some cases that data have been complemented/enhanced by data from zbMATH Open. This attempts to reflect the references listed in the original paper as accurately as possible without claiming completeness or a perfect matching.