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On the mean gyration radius and the radial distribution function of ring polymers with excluded volume under a topological constraint. (English) Zbl 1092.82055

Calvo, Jorge A. (ed.) et al., Physical and numerical models in knot theory. Including applications to the life sciences. Hackensack, NJ: World Scientific (ISBN 981-256-187-0/hbk). Series on Knots and Everything 36, 399-419 (2005).
Summary: We discuss the competition between the topological effect and the excluded volume effect on the average size of ring polymers with a fixed knot, reviewing some simulation results of the authors [Phys. Rev. E 64, 020801 (2001)]. Under a topological constraint, the average size of ring polymers can be much larger than that of no topological constraint. However, the effective expansion depends strongly on the excluded-volume parameter. We also discuss the radial distribution functions of segments of ring polymers with fixed knots. The numerical results of the radial distributions suggest that a topological constraint on ring polymers effectively leads to an entropic repulsion among polymer segments.
For the entire collection see [Zbl 1085.57002].

MSC:

82D60 Statistical mechanics of polymers
57M25 Knots and links in the \(3\)-sphere (MSC2010)
92C40 Biochemistry, molecular biology