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The effect of a phase transition on the boundary conditions for rarefied gases. (English. Russian original) Zbl 0913.76080

J. Appl. Math. Mech. 60, No. 5, 753-758 (1996); translation from Prikl. Mat. Mekh. 60, No. 5, 761-767 (1996).
Summary: We calculate the entropy production at the interface between a liquid and a binary vapour-gas mixture by using a phenomenological approach. The consideration is confined to the case of the mixture flow over a slightly curved surface, the radius of curvature of which is much larger than the mean free path of the gas molecules. The presence, close to the interface, of kinetic boundary layers in which mass, momentum and energy transfer occurs, is borne in mind. Using the entropy production obtained, we construct a system of phenomological equations for scalar, vector and tensor surface fluxes and forces. Finally, we discuss new effects which arise from the non-equilibrium thermodynamic relations obtained.

MSC:

76P05 Rarefied gas flows, Boltzmann equation in fluid mechanics
82C26 Dynamic and nonequilibrium phase transitions (general) in statistical mechanics
82C40 Kinetic theory of gases in time-dependent statistical mechanics
Full Text: DOI

References:

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