Summary: The paper presents a method for testing transport of composite contacts materials under electrical arc conditions at high currents and for polarized electrodes. Tests and the discussion of results were carried out for silver-metal, silver-metal oxide and silver-tungsten carbide contact materials. Additionally, tungsten electrode was used as the second contact which was either cathode or anode. Spectrometric analysis of arc erosion components transported onto the second electrode and into the surroundings was carried out.