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We provide a graphical method to describe and analyze non-Gaussian quantum states using a hypergraph framework. These states are pivotal resources for quantum computing, communication, and metrology, but their characterization is hindered by their complex high-order correlations. The formalism encapsulates transformation rules for any Gaussian unitary operation and local quadrature measurement, offering a visually intuitive tool for manipulating such states through experimentally feasible pathways. Notably, we develop methods for the generation of complex hypergraph states with more or higher-order hyperedges from simple structures through Gaussian operations only, facilitated by our graphical rules. We present illustrative examples on the preparation of non-Gaussian states rooted in these graph-based formalisms, revealing their potential to advance continuous-variable general quantum computing capabilities.

Increasing the number of entangled entities is crucial for achieving exponential computational speedups and secure quantum networks. Despite recent progress in generating large-scale entanglement through continuous-variable (CV) cluster states, translating these technologies to photonic chips has been hindered by decoherence, limiting the number of entangled entities to 8. Here, we demonstrate 60-mode CVcluster states in a chip-based optical microresonator pumped by chromatic lasers. Resonantly-enhanced four-wave mixing processes establish entanglement between equidistant spectral quantum modes (qumodes), forming a quantum analogue of optical frequency combs. Decoherence is minimized to achieve unprecedented two-mode raw squeezing (>3 dB) from a chip. Using bichromatic and trichromatic pump lasers, we realize one- and two-dimensional cluster states with up to 60 qumodes. Our work provides a compact and scalable platform for constructing large-scale entangled quantum resources, which are appealing for performing computational and communicational tasks with quantum advantages.

Quantum networks play an extremely important role in quantum information science, with application to quantum communication, computation, metrology and fundamental tests. One of the key challenges for implementing a quantum network is to distribute entangled flying qubits to spatially separated nodes, at which quantum interfaces or transducers map the entanglement onto stationary qubits. The stationary qubits at the separated nodes constitute quantum memories realized in matter while the flying qubits constitute quantum channels realized in photons. Dedicated efforts around the world for more than twenty years have resulted in both major theoretical and experimental progress towards entangling quantum nodes and ultimately building a global quantum network. Here, we review the development of quantum networks and the experimental progress over the past two decades leading to the current state of the art for generating entanglement of quantum nodes based on various physical systems such as single atoms, cold atomic ensembles, trapped ions, diamonds with Nitrogen-Vacancy centers, solid-state host doped with rare-earth ions, etc. Along the way we discuss the merits and compare the potential of each of these systems towards realizing a quantum network.

Multiqubit entanglement is an indispensable resource for quantum information science. In particular, the entanglement of photons is of conceptual interest due to its implications in measurement-based quantum computing, communication, and metrology. The traditional way of spontaneous parametric down-conversion already demonstrates entanglement of up to a dozen photons but is hindered by its probabilistic nature. Here, we experimentally demonstrate an efficient approach for multi-photon generation with a Rydberg superatom, a mesoscopic atomic ensemble under Rydberg blockade. Using it as an efficient single-photon interface, we iterate the photon creation process that gives rise to a train of temporal photonic modes entangled in photon number degree. We detect the multiphoton entanglement via converting the photon number degree to a time-bin degree. Photon correlations verify entanglement up to 12 modes. The efficiency scaling factor for adding one photon is 0.27, surpassing previous results, and can be increased significantly without fundamental limitations.

A cold atomic ensemble suits well for optical quantum memories, and its entanglement with a single photon forms the building block for quantum networks that give promise for many revolutionary applications. Efficiency and lifetime are among the most important figures of merit for a memory. In this paper, we report the realization of entanglement between an atomic ensemble and a single-photon with subsecond lifetime and high efficiency. We engineer dual control modes in a ring cavity to create entanglement and make use of 3-dimensional optical lattice to prolong memory lifetime. The memory efficiency is 38% for 0.1 second storage. We verify the atom-photon entanglement after 1 second storage by testing the Bell inequality with a result of $S=2.36\pm0.14$.

Quantum internet will enable a number of revolutionary applications. It relies on entanglement of remote quantum memories over long distances. Despite enormous progresses so far, the maximal physical separation achieved between two nodes is 1.3 km, and challenges for long distance remain. Here we make a significant step forward by entangling two atomic ensembles in one lab via photon transmission through metropolitan-scale fibers. We use cavity enhancement to create bright atom-photon entanglement, and harness quantum frequency conversion to shift the atomic wavelength to telecom. We realize entanglement over 22 km field-deployed fibers via two-photon interference, and entanglement over 50 km coiled fibers via single-photon interference. Our experiment can be extended to physically separated nodes with similar distance as a functional segment for atomic quantum networks, thus paving the way towards establishing atomic entanglement over many nodes and over much longer distance.

Quantum network has significant applications both practically and fundamentally. A hybrid architecture with photons and stationary nodes is highly promising. So far, experimental realizations are limited to two nodes with two photons. Going beyond state of the art by entangling many photons with many quantum nodes is highly appreciated. Here, we report an experiment realizing hybrid entanglement between three photons and three atomic-ensemble quantum memories. We make use of three similar setups, in each of which one pair of photon-memory entanglement with high overall efficiency is created via cavity enhancement. Through three-photon interference, the three quantum memories get entangled with the three photons. Via measuring the photons and applying feedforward, we heraldedly entangle the three memories. Our work demonstrates the largest size of hybrid memory-photon entanglement, which may be employed as a build block to construct larger and complex quantum network.

Interference of multiple photons via a linear-optical network has profound applications for quantum foundation, quantum metrology and quantum computation. Particularly, a boson sampling experiment with a moderate number of photons becomes intractable even for the most powerful classical computers, and will lead to "quantum supremacy". Scaling up from small-scale experiments requires highly indistinguishable single photons, which may be prohibited for many physical systems. Here we experimentally demonstrate a time-resolved version of boson sampling by using photons not overlapping in their frequency spectra from three atomic-ensemble quantum memories. Time-resolved measurement enables us to observe nonclassical multiphoton correlation landscapes. An average fidelity over several interferometer configurations is measured to be 0.936(13), which is mainly limited by high-order events. Symmetries in the landscapes are identified to reflect symmetries of the optical network. Our work thus provides a route towards quantum supremacy with distinguishable photons.

We demonstrate deterministic generation of two distinct collective excitations in one atomic ensemble, and we realize the Hong-Ou-Mandel interference between them. Using Rydberg blockade we create single collective excitations in two different Zeeman levels, and we use stimulated Raman transitions to perform a beam-splitter operation between the excited atomic modes. By converting the atomic excitations into photons, the two-excitation interference is measured by photon coincidence detection with a visibility of 0.89(6). The Hong-Ou-Mandel interference witnesses an entangled NOON state of the collective atomic excitations, and we demonstrate its two times enhanced sensitivity to a magnetic field compared with a single excitation. Our work implements a minimal instance of Boson sampling and paves the way for further multi-mode and multi-excitation studies with collective excitations of atomic ensembles.