The minimal excludant (mex) of a partition was introduced by Grabner and Knopfmacher under the name ‘least gap’ and was recently revived by Andrews and Newman. It has been widely studied in recent years together with the complementary partition statistic maximal excludant (maex), first introduced by Chern. Among such recent works, the first and second authors along with Maji introduced and studied the r-chain minimal excludants (r-chain mex) which led to a new generalization of Euler's classical partition theorem and the sum-of-mex identity of Andrews and Newman. In this paper, we first give combinatorial proofs for these two results on r-chain mex. Then we also establish the associated identity for the r-chain maximal excludant, recently introduced by the first two authors and Maji, both analytically and combinatorially.